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Some Basic Concepts of Chemistry

33 NEET-UG practice questions on Some Basic Concepts of Chemistry, part of Chemistry. The first 25 are below; the first 5 with answers and explanations (tap Show answer after you have chosen), the rest in Learn with a free account.

  1. Question 1 · Hard

    A 10 mL mixture of CH₄ and C₂H₆ burns completely in excess oxygen and gives 14 mL of CO₂. All volumes are at the same temperature and pressure. Find the volume of O₂ consumed.

    1. A35 mL
    2. B26 mL
    3. C20 mL
    4. D28 mL
    Show answer

    Answer: B · 26 mL

    Let CH₄ = x and C₂H₆ = y: x + y = 10 and x + 2y = 14, so y = 4 mL and x = 6 mL. Oxygen used = 6 × 2 + 4 × 3.5 = 26 mL. Check by atoms: 14 CO₂ need 28 O, and 48 H give 24 H₂O needing 24 O, a total of 52 O = 26 O₂.

    • A: This treats the whole mixture as C₂H₆.
    • C: This treats the whole mixture as CH₄.
    • D: This counts the oxygen in CO₂ only and forgets the oxygen in the water formed.

    Remember this

    At the same temperature and pressure, gas volumes combine in the mole ratio of the equation (Gay-Lussac's law).

  2. Question 2 · Medium

    Ethanol (23 g) is dissolved in water (54 g). What is the mole fraction of ethanol in this solution? (C₂H₅OH = 46, H₂O = 18)

    1. A0.143
    2. B0.167
    3. C0.857
    4. D0.299
    Show answer

    Answer: A · 0.143

    Ethanol = 23/46 = 0.5 mol and water = 54/18 = 3 mol. Mole fraction of ethanol = 0.5/(0.5 + 3) = 1/7 = 0.143.

    • B: This divides by the moles of water alone, not the total moles.
    • C: This is the mole fraction of water.
    • D: This is the mass fraction of ethanol, 23/77.

    Remember this

    Mole fraction divides by the total moles of all components, and the fractions in a solution add up to 1.

  3. Question 3 · Easy

    Which concentration term of a solution changes with temperature?

    1. AMolality
    2. BMolarity
    3. CMass per cent
    4. DMole fraction
    Show answer

    Answer: B · Molarity

    Molarity is moles per litre of solution, and the volume of a solution changes with temperature. The other three are built only from masses or moles, which do not change on heating.

    • A: Molality uses the mass of solvent, which does not change with temperature.
    • C: Mass per cent is a ratio of masses, which does not change with temperature.
    • D: Mole fraction is a ratio of moles, which does not change with temperature.

    Remember this

    A concentration term that has volume in it depends on temperature; a term based only on mass or moles does not.

  4. Question 4 · Medium

    An organic liquid contains 54.5% C, 9.1% H and 36.4% O by mass, and its molar mass is 88 g/mol. Identify its molecular formula. (C = 12, H = 1, O = 16)

    1. AC₅H₁₂O
    2. BC₃H₄O₃
    3. CC₄H₈O₂
    4. DC₂H₄O
    Show answer

    Answer: C · C₄H₈O₂

    Dividing by atomic masses gives C 4.54, H 9.1 and O 2.275, a ratio of 2:4:1, so the empirical formula is C₂H₄O with mass 44. Since 88/44 = 2, the molecular formula is C₄H₈O₂.

    • A: This also has mass 88 but does not fit the 2:4:1 atom ratio.
    • B: This has mass 88 but does not fit the 2:4:1 atom ratio.
    • D: This is the empirical formula, with mass 44 rather than 88.

    Remember this

    Molecular formula = empirical formula × (molar mass / empirical formula mass).

  5. Question 5 · Hard

    An aqueous NaOH solution is 2 M and has a density of 1.08 g/mL. Calculate its molality. (NaOH = 40)

    1. A1.85 m
    2. B2.00 m
    3. C1.72 m
    4. D2.16 m
    Show answer

    Answer: B · 2.00 m

    One litre of solution has a mass of 1080 g and contains 2 × 40 = 80 g of NaOH, so the water is 1000 g = 1 kg. Molality = 2 mol / 1 kg = 2.00 m. Check by formula: m = M/(d − M × molar mass/1000) = 2/(1.08 − 0.08) = 2.

    • A: This divides by the solution mass, forgetting to remove the solute.
    • C: This adds the solute mass to the solution mass instead of subtracting it.
    • D: This multiplies molarity by density instead of finding the solvent mass.

    Remember this

    For molality, subtract the solute mass from the solution mass; the density alone does not give the solvent mass.

  6. Question 6 · Medium

    Arrange the following samples in increasing order of the total number of atoms present. (H = 1, He = 4, N = 14, O = 16) A. 4 g of He B. 9 g of H₂O C. 28 g of N₂ D. 8 g of O₃

    1. AD, B, A, C
    2. BC, B, A, D
    3. CA, D, B, C
    4. DD, A, B, C

    Answer and explanation in LearnFree account

  7. Question 7 · Easy

    A sample of methane, CH₄, has a mass of 8 g. How many moles of hydrogen atoms does it contain? (C = 12, H = 1)

    1. A2 mol
    2. B0.5 mol
    3. C1 mol
    4. D4 mol

    Answer and explanation in LearnFree account

  8. Question 9 · Medium

    Given below are two statements: Statement I: The mole fraction of a component in a solution has no units and does not depend on temperature. Statement II: The molarity of an aqueous solution increases when the solution is warmed. Choose the correct answer.

    1. AStatement I is incorrect but Statement II is correct
    2. BStatement I is correct but Statement II is incorrect
    3. CBoth Statement I and Statement II are correct
    4. DBoth Statement I and Statement II are incorrect

    Answer and explanation in LearnFree account

  9. Question 10 · Medium

    Aluminium (10.8 g) is heated with chlorine (21.3 g) until the reaction stops: 2Al + 3Cl₂ → 2AlCl₃ What mass of AlCl₃ forms? (Al = 27, Cl = 35.5)

    1. A26.7 g
    2. B53.4 g
    3. C32.1 g
    4. D40.05 g

    Answer and explanation in LearnFree account

  10. Question 11 · Medium

    Butane burns completely in oxygen: a C₄H₁₀ + b O₂ → c CO₂ + d H₂O For the balanced equation in the lowest whole numbers, what are a, b, c and d, in that order?

    1. A2, 13, 8, 10
    2. B2, 13, 8, 5
    3. C1, 9, 4, 5
    4. D1, 13, 4, 5

    Answer and explanation in LearnFree account

  11. Question 12 · Hard

    Strong heating of an 18.4 g mixture of CaCO₃ and MgCO₃ decomposes both carbonates completely to their oxides and gives 8.8 g of CO₂. What mass of CaCO₃ was in the mixture? (Ca = 40, Mg = 24, C = 12, O = 16)

    1. A9.2 g
    2. B8.4 g
    3. C16.8 g
    4. D10 g

    Answer and explanation in LearnFree account

  12. Question 13 · Medium

    Concentrated hydrochloric acid in a laboratory bottle is 36.5% HCl by mass and has a density of 1.2 g mL⁻¹. Its molarity is (HCl = 36.5 g mol⁻¹)

    1. A14.4 M
    2. B10 M
    3. C12 M
    4. D15.7 M

    Answer and explanation in LearnFree account

  13. Question 14 · Medium

    A chemist mixes 100 mL of 0.3 M HCl with 200 mL of 0.6 M HCl. Assuming the volumes are additive, the molarity of the mixture is

    1. A0.45 M
    2. B0.9 M
    3. C0.5 M
    4. D0.75 M

    Answer and explanation in LearnFree account

  14. Question 15 · Easy

    Limestone is mainly calcium carbonate, CaCO₃. What is the mass per cent of calcium in pure CaCO₃? (Ca = 40, C = 12, O = 16)

    1. A60%
    2. B12%
    3. C40%
    4. D48%

    Answer and explanation in LearnFree account

  15. Question 16 · Medium

    A sealed vessel holds 28 g of N₂ and 3 g of H₂. They react by N₂ + 3H₂ → 2NH₃ until one reactant is used up. Which reactant is left over, and how much of it remains? (N = 14, H = 1)

    1. A7 g of N₂
    2. B14 g of N₂
    3. C1 g of H₂
    4. DNone; both are used up exactly

    Answer and explanation in LearnFree account

  16. Question 17 · Medium

    A laboratory sample of sulphuric acid is 49% H₂SO₄ by mass and has a density of 1.5 g mL⁻¹. What is its molarity? (H₂SO₄ = 98 g mol⁻¹)

    1. A7.5 M
    2. B9.8 M
    3. C3.3 M
    4. D5.0 M

    Answer and explanation in LearnFree account

  17. Question 18 · Hard

    An organic compound contains only carbon, hydrogen and oxygen. Complete combustion of 0.30 g of it gives 0.44 g of CO₂ and 0.18 g of H₂O, and its vapour density is 30. What is its molecular formula? (C = 12, H = 1, O = 16)

    1. AC₂H₄O₂
    2. BC₄H₈O₄
    3. CC₃H₈O
    4. DCH₂O

    Answer and explanation in LearnFree account

  18. Question 19 · Easy

    A sample of carbon dioxide weighs 4.4 g. How many molecules of CO₂ does it contain? (C = 12, O = 16, N_A = 6.0 × 10²³ mol⁻¹)

    1. A2.6 × 10²⁴
    2. B1.8 × 10²³
    3. C6.0 × 10²³
    4. D6.0 × 10²²

    Answer and explanation in LearnFree account

  19. Question 20 · Medium

    Magnesium ribbon (6.0 g) is burnt in a closed vessel containing 8.0 g of oxygen gas: 2Mg + O₂ → 2MgO What mass of magnesium oxide forms when the limiting reagent is used up? (Mg = 24, O = 16)

    1. A14 g
    2. B5 g
    3. C20 g
    4. D10 g

    Answer and explanation in LearnFree account

  20. Question 21 · Medium

    Given below are two statements: Statement I: Hydrogen combines with oxygen to form water and hydrogen peroxide; for a fixed mass of hydrogen, the masses of oxygen in these two compounds are in the ratio 1 : 2. Statement II: At the same temperature and pressure, 1 volume of nitrogen reacts with 3 volumes of hydrogen to give 2 volumes of ammonia, in line with Gay Lussac's law of gaseous volumes. Choose the correct answer.

    1. ABoth Statement I and Statement II are correct
    2. BStatement I is correct but Statement II is incorrect
    3. CBoth Statement I and Statement II are incorrect
    4. DStatement I is incorrect but Statement II is correct

    Answer and explanation in LearnFree account

  21. Question 22 · Hard

    When 10 mL of a gaseous hydrocarbon is burnt completely, it uses 55 mL of oxygen and gives 40 mL of carbon dioxide, all volumes being measured at the same temperature and pressure. How many hydrogen atoms are there in one molecule of the hydrocarbon?

    1. A10
    2. B22
    3. C3
    4. D6

    Answer and explanation in LearnFree account

  22. Question 23 · Medium

    When 100 mL of 0.20 M AgNO₃ is mixed with 100 mL of 0.10 M NaCl, silver chloride precipitates. What mass of AgCl forms? (AgCl = 143.5 g mol⁻¹)

    1. A14.35 g
    2. B2.870 g
    3. C0.7175 g
    4. D1.435 g

    Answer and explanation in LearnFree account

  23. Question 24 · Easy

    One atomic mass unit (u) is defined as exactly

    1. Aone-twelfth of the mass of one carbon-12 atom
    2. Bthe mass of one proton
    3. Cthe mass of one hydrogen-1 atom
    4. Done-sixteenth of the mass of one oxygen-16 atom

    Answer and explanation in LearnFree account

  24. Question 25 · Easy

    What is the mass of 0.25 mol of glucose, C₆H₁₂O₆? (C = 12, H = 1, O = 16)

    1. A7.5 g
    2. B720 g
    3. C45 g
    4. D4.5 g

    Answer and explanation in LearnFree account

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